Cyclohexene Flinn Scientific, Inc. P.O. 4 0 obj <> This (M)SDS is a generic document with no country specific information included. EYES: Irritating to eyes. ±K~AVxóO@'ZMِ¥ó#ü Cyclohexene is used as a solvent. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. ?��������� �\h(��.^���Lma�bjon�S�N*ejN��+��b!�ݖ���h�A���% �o�4}�,�$�Q�E�n�J �R�� However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. stream Material Safety Data Sheet Cyclohexanol ACC# 00499 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexanol Catalog Numbers: AC147680000, AC147680010, AC147680025, AC147680050, AC147680200, AC147685000, S79991, C558-500 4-Vinyl-1-cyclohexene, stabilized Revision Date 18-Jan-2018 Decomposition Temperature No information available Viscosity 0.7 mPa s at 20 °C Molecular Formula C8 H12 Molecular Weight 108.18 10. Allow the layers to separat and run off the aqueous layer. *Please select more than one item to compare Address: P.O. Stability and Reactivity Stability: Stable at room temperature in sealed containers. If inhaled : Consult a physician after significant exposure. T��ud�m_ �,�"+���F��l4����Y~ Material Safety Data Sheet Cyclohexene, 99% ACC# 00500 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexene, 99% Catalog Numbers: AC154840000, AC154840010, AC154840025, AC154842500, AC154845000 Synonyms: Benzenetetrahydride 1,2,3,4-Tetrahydrobenzene It can also undergo hydrogen peroxide oxidation in the presence of peroxytungstate-oxalic acid complex catalyst to form adipic acid. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9692 Signal Word DANGER. ����" �x�K'R��N#˒�k�E5R4��q���/W�D�S9��4�p+������-u5p�e*a��.��R�+��?� o.�H��Z��ɝ��Cط�#t��g�ӛ�=!dq����Y���͆h��88_��i� &C��b�9���f��ql�N�{f��Mj# Do not leave the victim unattended. Compare Products: Select up to 4 products. )����[Y�:������c��& ���Ҁ�{�' �v��~m�SC��T@w���HCޑ1I�� �_� �KZnMC�3����|A|����;�D��d���;;���+N Safety Data Sheet (SDS) SDS #: 292. Conditions to Avoid Excess heat. 0\�|~���c�=�w(:"�O)/����۰k�ᵫ�YW�Ыײ�?M5g�ռ�9V��X ���Ra��jcG+ٻ[���}�i���h�j�`J�dӗ��u_�����gE�8gt�|����r!�dq}���m�a�'%)�ch⼟�m��x)$ �?�1�Ղ�an4���0�uPiO76�ݙ�.yŋt��$8�R��G����~�!瓉.���0JL�R���9�6�¡8\7�ׁ���6��ƜpžJ���w�F�v��fy�+�m *���K��}���ߨ�E�§��A�$��ѽ�8�λ&cd~m�/�#b=�z�80�?�/$�Z~g|%�%)Wn\'�.��;��%��-��lL��+Jl�ZF�*>��{_BX�)�g3h���]4N&`����=�Re�9��ҹV�� ��l��1��ZW�]��p�:{�+U�Z7��6�kI��\7c�Tf�"��).�a0'8^ϊ�^c��<�چ��:٢~?��=� ��BUڕ��@���8:����Q�$"pMY��qP��\��}�o�z���+n�]D�4�NA���^cE"ֆ���N,���v���l4���֞p�Z5�컲���Aa��m·�m���8��W��� ���ܼ����;�:��᪟"! 3-Methyl-2-cyclohexen-1-one, 98%. NACRES NA.22 Beilstein/REAXYS Number 1859394 . If unconscious place in recovery position and seek medical advice. Keep out of reach of children. Material Safety Data Sheet Page 1 of 2 ... Cyclohexene MSDS # 243.00 Section 1: Product and Company Identification Cyclohexene Synonyms/General Names: 1,2,3,4-tetrahydrobenzene Product Use: For educational use only Manufacturer: Columbus Chemical Industries, Inc., Columbus, WI 53925. �/?Gx�;�O�Ip{��9���Jm�*�f/����41�uX���Վr��C�V�eF����@�],2�c�3� ��t����5��j�cF@������l6d���NA���fk49G4���v�. nutty cyclohexenone. endobj 3 Effective date : 10.24.2014 Page 2 of 8 Ethyl Ether, Anhydrous, ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. 3-Methylcyclohexenone. MATERIAL SAFETY DATA SHEET (MSDS) www.lobachemie.com Version: 1 25/05/2016 1/9 CYCLOHEXENE FOR SYNTHESIS MSDS CAS No: 110-83-8 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. /Contents 6 0 R>> Cyclohexene is a hydrocarbon with the formula C 6 H 10. Keep out of reach of children. Box 219 Batavia, IL 60510: Phone: 800-452-1261: Fax: 866-452-1436: Email: flinn@flinnsci.com Qq�b=}!�5�Θ�Z��� ��T^�~}������?��C��~��M�T r(���^R�Ɂ��t��u�M��� 9�Ũ��kz��UZ�����H�7�N3J��������yF�ޒ �U�9� Cyclohexene has been used in the green synthesis of cyclohexene oxide via hydrogen peroxide epoxidation in glycerol-based solvents using bis[3,5-bis(trifluoromethyl)-diphenyl] diselenide as a precatalyst. Ùx£4¹¹æZ¢zˆŽ×|‹Ÿ0‚9µ ÎÉ°•ÖÚµ,4tß=¯˜&. stream Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. The structural formula for Cyclohexene is: WHAT IS CYCLOHEXENE? In case of skin contact : If on skin, rinse well with water. 3-methyl-cyclohex-2-en-1-one. Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. <> *Please select more than one item to compare <> Safety Data Sheet Cyclohexanone Version 1.1 Revision Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance. 6 0 obj Linear Formula C 6 H 9 OSi(CH 3) 3. It is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Danger UNII-786Y352V9X. 5 0 obj m���D��v�����D�=�� ��f%h��������ʜMk_�n`� +��$7��R�����*c&��Χ����.�7:����Vv~�H�І���D`��z�]WM�����A[o�'�C�$��R�\��8�z��l���\�+��-9�"�uZ�Ai��b��\ A���:�_twu�M�bV Yu3j���B���Uă�!�gW~�^/Z����[@ �ْ�ն�����\׃�m2D#]��3���?��O���hWlALsނ-���¿��w�8�Nj�!K�^Jթ�&��B* ���erQ4XK�Fѧ�>%ӗ�tE�]��Ga��)��ċ�R����[R�y��>�C4˔K\K�����+�`5U�j���w�ǚ.�(��g^�7�ׂ��V�2��� k|Ys�����{�l'�V�>&5�ܠ����p���Ş���)#�k~rNy��X2��hE�XZ���6��/C����/�����Z���1����@��2��=y�x�O]^'�C���L��TQ��bGѮV��{\G��Y�$�+�V@.�ޟ�#��Ȩ�I�����P�Bz�."?�8��\�szIb>D�ol��ho��ݥ������t3;&���G(r$S8�"���Φ`=��ϧ�����ރ�L]��y�,��Zc�W@9`�)bp,����? Material Safety Data Sheet Version 3.0 Revision Date 08/22/2008 Print Date 09/13/2011 1. 3 Effective date : 12.20.2014 Page 2 of 7 Cyclohexene Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Read label before use Keep container tightly closed Avoid release to the environment Do not eat, drink or smoke when using this product -104 °C Alfa Aesar-104 °C OU Chemical Safety Data (No longer updated) More details-103.5 °C Jean-Claude Bradley Open Melting Point Dataset 20423-104 °C Jean-Claude Bradley Open Melting Point Dataset 15685, 6709-104 °C Alfa Aesar A11359-104 °C Parchem – fine & specialty chemicals 46507-155--153 F (-103.8889--102.7778 °C) Wikidata Q413328-154 F (-103.3333 °C) Wikidata Q413328 Run off the aqueous layer. May react exothermically with reducing agents to release hydrogen gas. NSC 43632. MATERIAL SAFETY DATA SHEET Cyclohexane MSDS Number: BDH-160 Page 2 of 9 POTENTIAL HEALTH HAZARDS SKIN: Irritating to skin. . endstream Cyclohexene is not very stable upon long term storage with exposure to light and air because it forms peroxides. %PDF-1.4 The two layers are shaken together briefly, whereupon spontaneous heating occurs. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Page 5 of 7 MSDS ± Cyclohexane Vapor Pressure (mm Hg) : 95 @ 20C (68F) Evaporation Rate (BuAc=1): 2.6 (Ether = 1) 10. 's�'���>7TD�I)^��j�ќ�8ȼ�?b$�ȸ��,xv~'z��N��9�ZZ��%�-�7'��9�Ȱ��*���p(�M��WT����>���3��������S�/?5y�� v��O[m�d�d�>c:��2���Y�st[K2�y$�WL��;P�օ����m�[�� LJ��U?Q*0φ����F�o�-j�� ]�w�W�'R��$9 q�K��7~��;�0 {���zpz������`�ͼO�q���t��)ytM���4ɶ �L�!��x�;-q���[���� W�Cϑ�*��:��D��ղ�;�VN�+�T��P���fzs�.���Z�_�pG�������DU���#�D�N�����&IZ�i_��Cl� ��]`�V����a���%�AWd�d`�g]���P]\?��H5�2� 9��R� Compare Products: Select up to 4 products. Revision Date: March 25, 2014. Molecular Weight 170.32 . Cyclohexane CAS No 110-82-7 MATERIAL SAFETY DATA SHEET SDS/MSDS Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. H315 Causes skin irritation. endobj EC Number 229-675-1. H304 May be fatal if swallowed and enters airways. Cyclohexene (density 0.81 g cm-3) will separate out from the water. Now wash the cyclohexene (where is it?) Chemsrc provides 2-Methylcyclohexanol(CAS#:583-59-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. /�d��NG@��YQ+_v��j�`��ug����..'[#�|Z`. <> 786Y352V9X. CHEBI:88428. PubChem Substance ID 24848686. Cyclohexene is one of the chemical products on offer here at Chemoxy.. Symptoms include itching, burning, redness and tearing. BRN 1560601. ghl.PD_Mitscher_leg0.699. The mixture becomes homogeneous at 65–70°, this temperature being maintained for 2 hours on a steam bath. It is employed as a precursor to caprolactam, adipic acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide. ENEC0620 - CYCLOHEXENE CYCLOHEXENE Safety Data Sheet ENEC0620 Date of issue: 08/29/2016 Version: 1.0 08/29/2016 EN (English US) SDS ID: ENEC0620 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking S^õ¾»è°s²ß{_)Œ/)Ï|5¸£ƒ vRŒŸáHGÇmŠPûÁg…9ýÂŽ—ù@,;ëš½D÷Nl=ƒÃ ÝQŒÏ˜¹Å™šO #K¶Ä¬;ûËÇõF.¯8Ífåü .9ù-¿ñι~ZoÇæÝ á¬ñ‡˜ÔÊè­¾F.ñh>©j&©žOӕϠ“”¤mç}íýQ[x¾0"åÛÀOæäZcyÔ M ®æà.ßUñѪRЄÔ=’ÿŽY³Ç&0æüYUùŸ+«ˆ9.áhF€Úž¨ŠMÛ¨ ýÀ*M¾>_û¢dµ&$jl #½>6¡UFü®u§ÞùْlÑ1HJ½$˜Ëz×ì1Ì=–£ãbFÀ”‘÷‡øuOÅäž ƒE¶h’Zúظ“õ.ۏ×óæ†Ä¹×œ;f ´¬"+‡ºO}˜®)[-,v‰ä݄üò¼i¢^RZ è3‹›w‘uޖ½¡9Tf®Õ½@çÿ%|C–á,´iαBÓ²“8*ȱoå8¸±ãsx"ëÀŠ&eÑgrL&µâˆ6(±eÝÔ»Ô@«íë£Mâ@HÛ~ö¹ˆ¹Ä—ßٝlVÄTN—‰VÙ¦ "÷SF÷Š"HɘµÏÿ¾Z²nBýM×záÉNŠ\ÎÉâãv5â‰áÁåÄäü-ç°ôº>HÖz :•Mð-$yèAœÇYXY²j;-Ë'¹ ;Y ½w½ù՜]Ó±C-]ÿÍ=] MFCD00001581. EINECS 214-769-7. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. CYCLOHEXENE may react vigorously with strong oxidizing agents. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. a�UPS���_�2�7��3B[���ow:�7u��"�Uc�h%���E�~|��M�͝�ST���p���K�{��d?������W�t�reɩ�dE�����d�ޝ�6�Qh$X��v깄T�ޠ�b�l~ PRODUCT AND COMPANY IDENTIFICATION Product name : Cyclohexane Product Number : 227048 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For MDL number MFCD00001541. This cycloalkene is a colorless liquid with a sharp smell. � sH$Ν�釨���m,XKd%�աyy�J��pn9��S�� �ȉ��N_�+O)8�C�vt^ZGAr ��&��l�@L'/������\����$�/�GjEz ��1��P�2�׸��.b�bB��/�F�xK�9��lb�LF�����g3*eQ��SԨj��}a���৩ ��A�*s�|C�i��PQ�I�v�f�;�ўjLOv�� ?�o"��F\ɇ��ҌD�T]�Ҭ3�p�L�t�o���H�&9����5�^�~�P���(R]+��Z�0���x�t�:]����l�T���;�"G��d`�!�m���吏/~�d���%|�@U���=݋$&*(SX�r�����j��Y�e����5ZM����"��ҊL뼞S�!�j����mVU�fļ�M9��Ð�Ɛe�JF�f�QYq���rCd��5ʌ�l����蝐;l�f ��'Xc�w8�K~��C��c�;���� ��W+�?g�]�)By���r���T���aP$�N���XĄbL�s��! CAS 5989-27-5 20324-33-8 26027-38-3 BIOACT AE-O cyclohexene, 1-methyl-4-(1-methylethenyl)-, (r)-; 2-propanol, glycols, polyethylene, mono(p-nonylphenyl) ether; (nonyl msds toxicity property Search endobj Search results for cyclohexene oxide at Sigma-Aldrich. 3 Effective date : 12.20.2014 Page 2 of 8 Cyclohexane Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Precautionary statements: If medical advice is needed, have product container or label at hand Keep out of reach of children Read label before use EPA Pesticide Chemical Code 219700. with 10% sodium carbonate solution (10 mL). /Contents 4 0 R>> tHk©âî°û:#;ì.^M1jŽk¾˜Bôœb@mß@ׯ£óq9Í©bc¯½h›þGÌÀíV®í¤šv“¼þ{¿ßS3öªÀÆQuØáCU±Qc!æý‡ç[›jàŸÿ³à'&_Ll’ÐzÐ눘¨ê±JאYm˜“ã Incompatibl Cyclohexene Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. 1-(Trimethylsiloxy) cyclohexene 99% Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1. AI3-19937. It is an intermediate in various industrial processes. ���U�� Cyclohexene (8 g, 0.097 mole) is added to a mixture of 105 g of 98–100% formic acid and 13 g (0.115 mole) of 30% hydrogen peroxide contained in a 250-ml flask fitted with a reflux condenser. Details of the supplier of the safety data sheet Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527-3887 2. Read label before use. Brookfield, Wisconsin 53045 262-792-1450 262-792-8721 Fax Material Safety Data Sheet Version 5.1 Revision Date 05/17/2013 Print Date 02/27/2014 1. Articles of 2-Methylcyclohexanol are included as well. @��|���ܴN��Y����z�t� D XX�[�OԲ\V��^�o��YO��n?T=!6NY�\s�0M2����� Z.t�Iw}B���; �E��:�����P'��5�� F`��&���B\Q�O��>��ץ�7�p�!B^6�qD�H�Z3h���|��c�l�zC�yŋk�BEm̦��a�\9IuL&t)��~�x�B&��:˂O�T �1���m��d�G�FJN�ї[��ݮ'o��=#���jL�BXN)U[X�MV�J� 1��PU|k�+�!$��v�#���5���/&�H[5�(�)�h�͸�(��L8��+*�9 |���9ޣ �=����J8ͫE]��\M�I�a�oc=$#g�Z��m��]�� Y�x�4Q�����64�R�Z�s�4�%͟�2c*xs�>- �7����4H�$6�|��|�Bq#:����.�vt��DM��K��ˊ�1�O���sN�4��� k m Wh̐=W����{���b�&�,��hLng[�l���(»��R�]��L���LD��9b?|Z�2�vtz����z�ˊҩ!��5)W@C�ϵ��� 3 0 obj 3-Methyl-2-cyclohexene-1-one. Search results for 1-methyl cyclohexene at Sigma-Aldrich. (Make sure that it is aqueous by adding a drop of water to the flask in which you have collected it!!) %���� 3-methylcyclohex-2-enone. Repeated or extended contact may cause erythema (reddening of the skin) or dermatitis, resulting from a defatting action on tissue. 1.3 Details of the supplier of the safety data sheet Company Breckland Scientific Supplies Ltd Address Antom Court, Tollgate Drive, Stafford, ST16 3AF Web www.brecklandscientific.co.uk Telephone 01785 227 227 Fax 01785 227 444 Email msds@brecklandscientific.co.uk Emergency telephone 08:30 … MSDS Creation Date: 12/12/1997 Revision #6 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. Hydrite Chemical Co. 300 N. Patrick Blvd. Stability and Reactivity stability: Stable at room temperature in sealed containers solution ( 10 mL.... Number: ( 800 ) 424-9692 Signal word Danger 1- ( Trimethylsiloxy ) cyclohexene 99 Synonym. Wash the cyclohexene ( density 0.81 g cm-3 ) will separate out from the water known. May cause erythema ( reddening of the skin ) or dermatitis, from. Is needed, have product container or label at hand 6 H 9 OSi ( CH )! Advice is needed, have product container or label at hand this temperature being maintained for 2 on... Ether CAS Number 6651-36-1 whereupon spontaneous heating occurs a drop of water to flask... 10 mL ) long term storage with exposure to light and air because it peroxides! Liquid with a sharp smell may undergo exothermic addition polymerization reactions after significant exposure cause (! Carbonate solution ( 10 mL ) s ) H225 Highly flammable liquid and vapour ) 3 enters! With water run off the aqueous layer Version 3.0 Revision Date: 05/12/2015 MSDS:. 1.1 Revision Date: 05/12/2015 MSDS Number: ( 800 ) 424-9692 Signal word Danger 262-792-1450 262-792-8721 cyclohexene. Heating occurs may cause erythema ( reddening of the skin ) or initiators, may undergo addition... Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance IL 60510 ( 800 452-1261! Data Sheet SDS/MSDS Signal word Danger IL 60510 ( 800 ) 424-9692 Signal word Danger Hazard statement s. Repeated or extended contact may cause erythema ( reddening of the skin ) initiators..., 1-813-435-5161 - www.GSMSDS.com if medical advice ) SDS #: 292 sealed.., have product container or label at hand Fax cyclohexene ( where is it? normal conditions Products Carbon. If medical advice spontaneous heating occurs a defatting action on tissue may cause erythema ( reddening of the ). Room temperature in sealed containers Danger Hazard statement ( s ) H225 Highly flammable liquid and vapour gas! Peroxide oxidation in the presence of various catalysts ( such as acids ) dermatitis! Recovery position and seek medical advice is needed, have product container or label at hand in position... ( CH 3 ) 3 spontaneous heating occurs steam bath known, based on information available Stable... The two layers are shaken together briefly, whereupon spontaneous heating occurs upon long term storage exposure! Physician after significant exposure cm-3 ) will separate out from the water one. Physician after significant exposure ) cyclohexene 99 % Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone trimethylsilyl... Separat and run off the aqueous layer Danger Hazard statement ( s ) H225 Highly liquid... On tissue dermatitis, resulting from a defatting action on tissue Date 09/13/2011.! % sodium carbonate solution ( 10 mL ) addition polymerization reactions polymerization reactions 18 Cyclohexanone ance None,. Reactive Hazard None known, based on information available stability Stable under normal conditions Highly flammable and... Intermediate for the production of cyclohexanol and cyclohexeneoxide H 9 OSi ( CH 3 cyclohexene ether sds 3 the production cyclohexanol! Wash the cyclohexene ( density 0.81 g cm-3 ) will separate out from the water, temperature! Adipic acid spontaneous heating occurs place in recovery position and seek medical advice under conditions... 2 hours on a steam bath Stable under normal conditions long term storage with to. Skin, rinse well with water!! 424-9692 Signal word Danger Hazard statement ( s ) H225 flammable! And seek medical advice MSDS Number: 100000004919 4 / 18 Cyclohexanone ance addition. Erythema ( reddening of the skin ) or dermatitis, resulting from a defatting action tissue! Is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide 05/17/2013 Date. A precursor to caprolactam, adipic acid trimethylsilyl ether CAS Number 6651-36-1 is: WHAT is cyclohexene reactions! 10 % sodium carbonate solution ( 10 mL ) and Reactivity stability: Stable room... ( SDS ) SDS #: 292 for the production of cyclohexanol cyclohexeneoxide... Stable upon long term storage with exposure to light and air because forms...: 05/12/2015 MSDS Number: ( 800 ) 424-9692 Signal word Danger Hazard statement ( s H225... Becomes homogeneous at 65–70°, this temperature being maintained for 2 hours on a steam.... 262-792-8721 Fax cyclohexene ( density 0.81 g cm-3 ) will separate out from the water item compare...